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Heteropolyoxometalate Catalyzed Selective Oxidation of Alcohols to CarbonylCompounds by Hydrogen Peroxide under Mild Condition |
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| รหัสดีโอไอ | |
| Creator | Uday Sankar Agarwalla |
| Title | Heteropolyoxometalate Catalyzed Selective Oxidation of Alcohols to CarbonylCompounds by Hydrogen Peroxide under Mild Condition |
| Publisher | Silpakorn University Research and Development Institute |
| Publication Year | 2560 |
| Journal Title | Silpakorn University Science and Technology Journal |
| Journal Vol. | 11 |
| Journal No. | 3 |
| Page no. | 25-31 |
| Keyword | Heteropolyoxometalate, Oxidation, Alcohols, Hydrogen peroxide |
| ISSN | 2586-842x |
| Abstract | Keggin-type heteropolyoxometalates have been used as catalysts for the oxidation of benzylic alcohols and secondary alcohols to the corresponding carbonyl compounds using environment-friendly H2 O2 as oxidant at room temperature. The catalysts used in this study exhibit high selectivity in the oxidation of alcohols with no over-oxidation and formationof carboxylic acids. For vanadium(V)-substituted heteropolyoxometalates [Hx-2PVx W12-xO40] 5- (x = 4 and 6), the catalytic activity decreased with the increase in number of vanadium atoms in the catalyst. |
