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Using reactive distillation for upgrading bio-oil from co-pyrolysisof palm kernel shell and palm empty fruit bunches |
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| รหัสดีโอไอ | |
| Creator | 1. Phonsan Saetiao 2. Sukritthira Rattanawilai 3. Songtham Photaworn 4. Kulchanat Prasertsit |
| Title | Using reactive distillation for upgrading bio-oil from co-pyrolysisof palm kernel shell and palm empty fruit bunches |
| Publisher | Research and Development Office, Prince of Songkla University |
| Publication Year | 2564 |
| Journal Title | Songklanakarin Journal of Science and Technology (SJST) |
| Journal Vol. | 43 |
| Journal No. | 4 |
| Page no. | 1115-1122 |
| Keyword | reactive distillation, co-pyrolysis, palm kernel shell, empty fruit bunches, upgrading bio-oil |
| URL Website | https://rdo.psu.ac.th/sjstweb/index.php |
| ISSN | 0125-3395 |
| Abstract | Due to the poor physical properties of raw bio-oil from pyrolysis, in this work reactive distillation was used to upgradevaporized bio-oil from selected co-pyrolysis of palm kernel shell and palm empty fruit bunches at 75%/25% mixing ratio byusing 10%Ni/HZSM-5 catalyst and ethanol at various reboiler temperatures. In the pyrolysis process, the feed temperature (biooil vapor and non-condensable gas) was in the range between 35 and 230 ?C. The reboiler temperature not only influenced theseparation of heavy oil from raw bio-oil, which would help minimize catalyst deactivation, but also possibly affected contacttime of reactants with catalyst via the residence time. The vaporized bio-oil was upgraded by esterification and acetalizationreactions producing levulinic acid ethyl ester, nonanoic acid ethyl ester, and 1,1-diethoxyethane. The physical characteristicsdensity, kinematic viscosity, water content, and pH were improved from those of the raw bio-oil. |
