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The synthesis of imprinted polymer sorbentfor the removal of mercury ions |
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| รหัสดีโอไอ | |
| Creator | 1. Djabal Nur Basir 2. Muhammad Ali Zulfikar 3. Muhammad Bachri Amran |
| Title | The synthesis of imprinted polymer sorbentfor the removal of mercury ions |
| Publisher | Research and Development Office, Prince of Songkla University |
| Publication Year | 2563 |
| Journal Title | Songklanakarin Journal of Science and Technology |
| Journal Vol. | 42 |
| Journal No. | 5 |
| Page no. | 1135-1141 |
| Keyword | removal, mercury, Hg-IIPs |
| URL Website | https://rdo.psu.ac.th/sjstweb/index.php |
| ISSN | 0125-3395 |
| Abstract | In order to remove mercury ions, Hg(II)-ion-imprinted polymers (Hg-IIPs) with silica core were synthesized by radicalpolymerization using complexes of Hg(II) ions with 3-mercaptopropyltrimethoxysilane ligands as a template, vinyltrimethoxysilane as a monomer, and ethylene glycol dimethacrylate as a crosslinker, in the molar ratio 1: 6: 6. Silica, thiol, vinyl,carbonyl, and Hg(II) in the synthesis process were detected through FTIR, SEM-EDS, TGA, and BET analyses. Using Hg-IIPs asthe sorbent, mercury ion removal was near optimal from a batch at pH 4 with an interaction time of 90 min, and gave 62.27 mg.g-1adsorption capacity. The capture by Hg-IIPs of Hg(II) ions in the presence of Pb(II), Cd(II), and Cu(II) ions in quaternarysolutions had the selectivity coefficients 46.92 for Hg/Cu, 16.82 for Hg/Cd, and 2.07 for Hg/Pb. |
