Crystalline silica in compressed rice hull coke ash
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Creator Takeshi OKUTANI
Title Crystalline silica in compressed rice hull coke ash
Contributor Eri ICHIKAWA, Hedeaki NAGAI, Toshitaka HASHIMOTO, Tsuyoshi MAKIHATA
Publisher Metallurgy and Materials Science Research Institute, Chulalongkorn University
Publication Year 2561
Journal Title Journal of Metals, Materials and Minerals
Journal Vol. 28
Journal No. 1
Page no. 30-38
Keyword Rice hull coke, Ash, Potassium Cristobalite, Respirable crystalline silica, Combustion
URL Website http://ojs.materialsconnex.com/index.php/jmmm/index
Website title Journal of Metals, Materials and Minerals
ISSN 8576149
Abstract Compressed rice hull coke was produced by compressing rice hulls ground to less than 200 ?m diameter at 1.22x106 N/m2 and 310?C with an oxygen deficient atmosphere. The compressed rice hull coke had a 5 cm outer diameter, a 1.5 cm inner diameter and 35 cm length. The density of the coke is 1.2, and, the heat value is 16570 kJทkg-1. In this study, 2 kg coke was combusted at the average temperature of 850?C for 104 min with a maximum temperature of 860?C. The ash was colored black-grey, and the form remained coke. The ash contained 95.4% silica with 9.2% cristobalite and 86.2% amorphous silica. The occupational exposure limits of respirable fraction of crystalline silica such as cristobalite and quartz in floating dust less than the diameter of 7 ?m is 0.025 mg/m3; however, no respirable cristobalite was detected during combustion of the compressed rice hull coke. Cristobalite was not present in floating dust because it melted during the crystallization of amorphous silica to cristobalite.
Metallurgy and Materials Science Research Institute, Chulalongkorn University ​

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