Advanced Oxidation Processes of Mature Landfill Leachate Containing Ferrous Ion
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Creator Arseto Yekti Bagastyo, Anita Dwi Anggrainy, Isna Nufussilma Tamas, Welly Herumurti
Title Advanced Oxidation Processes of Mature Landfill Leachate Containing Ferrous Ion
Publisher The Thai Society of Higher Education Institutes on Environment
Publication Year 2561
Journal Title EnvironmentAsia
Journal Vol. 11
Journal No. 1
Page no. 230-242
Keyword COD, Fe2+, Fenton, H2O2, Leachate, pH
ISSN 2586-8861
Abstract Advanced Oxidation Process by means of Fenton-like process was performed to treat mature landfill leachate containing 0.0069 M of Ferrous iron. Hydrogen peroxide was added to promote the oxidation of leachate at specific Fe2+/H2O2 molar ratio, and conducted at pH 3 and pH 4 in completely stirred batch operated for 240 min. The highest removal of organic measured as COD was 97%, achieved at Fe2+/H2O2 molar ratio of 1:5 and pH 3. Although the presence of chloride ions interfere the oxidation process, the removal of COD was obviously affected at the molar ratio of 1:15 and 1:20 at both pH, whereas the other molar ratios were unclear due to possible generation of intermediate species. While pH 3 was preferable for the Fenton-like process, neutralisation/precipitation at pH 7 and/or pH 8 was required as polishing treatment of the effluents. This may limit the application of Fenton-like process for alkaline leachate treatment.
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