Effects of Calcination Treatment of Diatomite on Dimethyl Ether Synthesis from Methanol
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Creator Watcharakorn Pranee
Title Effects of Calcination Treatment of Diatomite on Dimethyl Ether Synthesis from Methanol
Contributor Pornsawan Assawasaengrat, Arthit Neramittagapong, Sutasinee Neramittagapong
Publisher TUENGR Group
Publication Year 2557
Journal Title International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies
Journal Vol. 5
Journal No. 1
Page no. 10-Jan
Keyword DME, renewable energy, methanol, acid catalyst.
URL Website http://tuengr.com
Website title International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies
ISSN 2228-9860
Abstract The synthesis of dimethyl ether via methanol dehydration over diatomite catalysts was investigated. The reactions were carried out in a fixed bed reactor. The effects of calcinations of diatomite on its catalytic performance were studied. Diatomite calcined at 500?C (DM500) gave the higher BET surface than fresh diatomite (DM) due to the loss of ignition. The rate of reaction over DM500 catalyst was lower than fresh DM due to the loss of active sites on the catalyst surface. However, the decrease of basicity of DM500 surface showed the higher selectivity to DME than fresh DM. The DM500 catalyst exhibits better DME yield than fresh DM catalyst, although it can be used as a selective catalyst for DME synthesis from methanol.
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