Treatment of Lignin Wastewater Using Peroxydisulfate Combined with Manganese Oxide-Loaded Biochar
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Creator 1. Glinsukol Suwannarat
2. Kemason Sontabam
3. Soraya Sawangying
4. Chompoonut Chaiyaraksa
Title Treatment of Lignin Wastewater Using Peroxydisulfate Combined with Manganese Oxide-Loaded Biochar
Publisher Thai Society of Higher Education Institutes on Environment
Publication Year 2565
Journal Title EnvironmentAsia
Journal Vol. 15
Journal No. 3
Page no. 143-151
Keyword Biochar, Lignin, Manganese oxide, Oxidation, Sodium peroxydisulfate
URL Website https://tshe.org/main/ea-journal-online
Website title EnvironmentAsia Journal
ISSN 1906-1714
Abstract The pulp and paper industry wastewater discharge into public water, it will cause water pollution problems. In this research, lignin contaminated synthetic wastewater with a COD value of 2,401 mg/L, and color intensity of 5,432 ADMI was treated using 150 mM sodium peroxydisulfate in combination with MnOx-loaded biochar (MnOx-B). The MnOx-B was produced by pyrolyzing corn core at 400 ?C for 4 hours without oxygen, then dipped in 40 mM manganese sulfate for 2 hours, and heated at 600?C for 30 min without oxygen. From the characterization of MnOx-B, the surface area, pore volume, pore size, and pH value at the zero-point charges of MnOx-B were 153 m2/g, 0.054 cm3/g, 1.11 nm, and 7.23, respectively.From the FTIR spectrogram, the peak assigned to Mn-O was observed. By applying 150 mM sodium peroxydisulfate and varying three parameters: MnOx-B dosage, initial wastewater pH, and reaction time, to treat lignin wastewater, the optimum experimental condition was obtained using 2 mg/L of MnOx-B, under pH of 8 for 45 min. The COD and color removal efficiencies were 73% and 90%, respectively. However, the quality of the treated wastewater did not yet pass the pulp and paper mills effluent standards of the Department of Industrial Works.
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