Ultra-Fine electrospun nanocomposite fibers of polymer-conductive polymer-nanoparticle
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Title Ultra-Fine electrospun nanocomposite fibers of polymer-conductive polymer-nanoparticle
Creator Prasit Pisesweerayos
Contributor Pitt Supaphol, Toemsak Srikhirin, Somsak Dangtip
Publisher Chulalongkorn University
Publication Year 2555
Keyword Polymers, Nanoparticles, Nanocomposites (Materials), โพลิเมอร์, อนุภาคนาโน, นาโนคอมพอสิต, ปริญญาดุษฎีบัณฑิต
Abstract In this research, ultra-fine fibers of polymer – conductive polymer blend, polymer – nanoparticle and polymer – conductive polymer – nanoparticle nanocomposite are fabricated, characterized, and investigated. Poly(3,4-ethylenedioxythiophene)/ poly(styrenesulfonate) blended with silver nanoparticles and correlated morphology are studied in details including the shapes and sizes of ultra-fine fibers. Electrospinning processes are considered as ultra-fine nanocomposite fibers of polymer-conductive polymer-nanoparticle formation. (This specific technique requires a syringe with a needle, a high voltage unit, and an aluminum foil (screen) as a collector.) The fabrication conditions for the electrospinning processes in the synthesis of ultra-fine nanocomposite fibers in this study are initially summarized whereby voltages between 12.5-22.5 kV are applied on a collecting distance of 15 cm in 5 minutes for random fiber formation and 20, 30, and 45 minutes of both aligned single fiber and aligned fiber mat formation which are generated from PVA blended with various PEDOT/PSS and AgNPs concentrations. The fiber diameters resulting from these permutations by the researcher in this review varied from 0.1 µm to 0.33 µm. This research illustrates the ultra-fine electrospun nanocomposite fibers of polymer-conductive polymer-nanoparticle which conduct higher electrical conductivity when loading higher PEDOT/PSS, and AgNPs concentrations to form ultra-fine fibers. The range of conductivity is varied from 4.23 to 92.18 S/cm, under the aligned single fibers technique, and from 1.94 to 13.57 S/cm, under the aligned fiber mat technique.
URL Website cuir.car.chula.ac.th
Chulalongkorn University

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