Structural characterization of cubic GaN films using transmission electron microscopy
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Title Structural characterization of cubic GaN films using transmission electron microscopy
Creator Surang Sumnavadee
Contributor Sakuntam Sanorpim, Boonchoat Paosawatyanyong
Publisher Chulalongkorn University
Publication Year 2553
Keyword Cubic GaN films, Transmission electron microscopy, ฟิล์มคิวบิกแกลเลียมไนไตรด์, จุลทรรศน์อิเล็กตรอนแบบทรานสมิชชัน
Abstract Cubic GaN (c-GaN) films grown by metalorganic vapor phase epitaxy were investigated using transmission electron microscopy (TEM) to verify effects of growth conditions on the film quality. The c-GaN films used in this study were grown on GaAs (001) and (311) oriented substrates with different growth temperatures of the GaN buffer layers (550-600℃). It is found that all the c-GaN grown films have a cubic structure as a main crystal structure. However, for higher growth temperature, hexagonal phase inclusions found to easily construct along the {111} facets of c-GaN associated with the formation of stacking faults (SFs) starting from the (111) step on the GaAs (001) grown surface. To reduce a generation of hexagonal phase in c-GaN films, growth temperature of a GaN buffer layer is optimized and affected on the formation of SFs in the c-GaN films. The best quality of c-GaN films grown on GaAs (001) substrates with cubic phase purity was achieved by the growth with the optimum growth temperature of GaN films of 900°C and low buffer growth temperature of 575℃. Besides, the c-GaN film on GaAs (311) substrate with identical growth conditions results in the presence of SFs but the hexagonal single crystal is invisible. These results demonstrate that c-GaN on GaAs (311) exhibits a better film quality with lower density of SFs compared to that in c-GaN on GaAs (001). This might be due to a difficulty of a generation of the (111) step on the GaAs (311) grown surface.
URL Website cuir.car.chula.ac.th
Chulalongkorn University

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