Degradation of polyethylene terephthalate bottles after long sunlight exposure
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Creator 1. Malinee Chaisupakitsin
2. Pitsamai Chairat-utai
3. Chutima Jarusiripot
Title Degradation of polyethylene terephthalate bottles after long sunlight exposure
Publisher Research and Development Office, Prince of Songkla University
Publication Year 2562
Journal Title Songklanakarin Journal of Science and Technology
Journal Vol. 41
Journal No. 2
Page no. 259-264
Keyword polyethylene terephthalate, degradation, PET bottle, contamination, carbonated soft drin
URL Website http://rdo.psu.ac.th/sjstweb/index.php
ISSN 0125-3395
Abstract Effects of sunlight on PET bottles degradation and liquid filled inside the bottles were studied. Three types of soft drinks filled in Polyethylene terephthalate (PET) bottles; drinking water in clear bottle, carbonated water in green, and pink bottles was left on the rooftop of building for 8 months. After long exposure to sunlight, the bottles' shapes were not changed, but the tensile strength of plastics decreased. Moreover, the enthalpy of fusion which corresponds to molecular rearrangement of plastics increased. The results from FTIR showed slightly increased of peak hydroxyl group at 3,400 cm-1 on outer surface of PET bottle. Sunlight slowly degraded the chemical structure on outer surface of PET bottle by photo-hydrolysis reaction. The pH of water for all samples changed from acid to base. By using Tollen's reagent, aldehyde was found clearly in drinking water after sunlight exposure, but was not observed in green and pink water.
Songklanakarin Journal of Science and Technology (SJST)

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